2-Benzyliminomethyl-4-chlorophenol
نویسندگان
چکیده
The title compound, C(14)H(12)ClNO, is a Schiff base derived from the condensation of equimolar quanti-ties of 5-chloro-salicylaldehyde and 1-benzyl-amine. The mol-ecule has a trans configuration with respect to the imine C=N double bond. The N atom is involved in an intra-molecular O-H⋯N hydrogen bond.
منابع مشابه
2-Benzyliminomethyl-6-bromo-4-chlorophenol
The title mol-ecule, C(14)H(11)BrClNO, adopts a trans configuration with respect to the C=N double bond. The dihedral angle between the two aromatic rings is 70.4 (5)°. An intra-molecular O-H⋯N hydrogen bond is observed between the hydroxyl and imine groups.
متن کامل2-[(E)-(5-Amino-2,3-diphenylquinoxalin-6-yl)iminomethyl]-4-chlorophenol
The title Schiff base compound, C(27)H(19)ClN(4)O, features two intra-molecular O-H⋯N and N-H⋯N hydrogen bonds involving the hydr-oxy and amino groups to generate S(6) and S(5) ring motifs, respectively. In the crystal structure, weak inter-molecular N-H⋯O and C-H⋯N inter-actions, together with π-π contacts [centroid-centroid distances = 3.6294 (11)-3.6881 (11) Å], link neighboring mol-ecules.
متن کامل2-[(E)-(4-Bromophenyl)iminomethyl]-4-chlorophenol
In the title compound, C13H9BrClNO, the dihedral angle between the substituted benzene rings is 44.25 (11)°. There are strong intra-molecular O-H⋯N hydrogen bonds, which generate S(6) rings, and also inter-molecular Cl⋯Cl [3.431 (3) Å] and Br⋯ Br [3.846 (1) Å] contacts. The crystal packing a C-H⋯O and C-H⋯π inter-actions.
متن کامل2-[(Adamantan-1-yl)aminomethyl]-4-chlorophenol hemihydrate
In the title compound, C17H22ClNO·0.5H2O, the water mol-ecule O atom resides on a twofold rotation axis. In the organic mol-ecule, the phenol group forms an intra-molecular O-H⋯N hydrogen bond. In the crystal, pairs of organic mol-ecules are hydrogen bonded through bridging solvent water mol-ecules, forming chains along the b-axis direction.
متن کاملBis(2-benzyliminomethyl-4,6-dihydroselenophenolato)iron(II)
In the title compound, [Fe(C(14)H(12)NOSe(2))(2)], the Fe(II) ion (site symmetry ) is four-coordinated by two N,O-bidentate Schiff base ligands, resulting in a slightly distorted trans-FeN(2)O(2) square-planar coordination for the metal ion.
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